Land application of tylosin and chlortetracycline swine manure: Impacts to soil nutrients and soil microbial community structure

The land application of aged chortetracycle (CTC) and tylosin-containing swine manure was investigated to determine associated impacts to soil microbial respiration, nutrient (phosphorus, ammonium, nitrate) cycling, and soil microbial community structure under laboratory conditions. Two silty clay loam soils common to southeastern South Dakota were used. Aerobic soil respiration results using batch reactors containing a soil-manure mixture showed that interactions between soil, native soil microbial populations, and antimicrobials influenced CO(2) generation. The aged tylosin treatment resulted in the greatest degree of CO(2) inhibition, while the aged CTC treatment was similar to the no-antimicrobial treatment. For soil columns in which manure was applied at a one-time agronomic loading rate, there was no significant difference in soil-P behavior between either aged CTC or tylosin and the no-antimicrobial treatment. For soil-nitrogen (ammonium and nitrate), the aged CTC treatment resulted in rapid ammonium accumulation at the deeper 40cm soil column depth, while nitrate production was minimal. The aged CTC treatment microbial community structure was different than the no-antimicrobial treatment, where amines/amide and carbohydrate chemical guilds utilization profile were low. The aged tylosin treatment also resulted in ammonium accumulation at 40 cm column depth, however nitrate accumulation also occurred concurrently at 10 cm. The microbial community structure for the aged tylosin was also significantly different than the no-antimicrobial treatment, with a higher degree of amines/amides and carbohydrate chemical guild utilization compared to the no-antimicrobial treatment. Study results suggest that land application of CTC and tylosin-containing manure appears to fundamentally change microbial-mediated nitrogen behavior within soil A horizons.     

Dimensionless correlations to predict VOC emissions from dry building materials

Based on the most recently published mass transfer model of volatile organic compound (VOC) emissions from dry building materials, it is found that the dimensionless emission rate and total emission quantity are functions of just four dimensionless parameters, the ratio of mass transfer Biot number to partition coefficient (Bi_m/K), the mass transfer Fourier number (Fo_m), the dimensionless air exchange rate (Nδ²/D_m) and the ratio of building material volume to chamber or room volume (Aδ/V). Through numerical analysis and data fitting, a group of dimensionless correlations for estimating the emission rate from dry building materials is obtained. The predictions of the correlations are validated against the predictions made by the mass transfer model. Using the correlations, the VOC emission rate from dry building materials can be conveniently calculated without having to solve the complicated mass transfer equations. Thus it is very simple to estimate VOC emissions for a given condition. The predictions of the correlations agree well with experimental data in the literature except in the initial few hours. Furthermore, based on the correlations, a relationship between the emission rates of a material in two different situations is deduced. With this relationship, the results for a given building material in a test chamber can be scaled to those under real conditions, if the dimensionless parameters are within the appropriate region for the correlations. The relationship also explicitly explains the impacts of air velocity, load ratio, and air exchange rate on the VOC emission rate, which determines the feasibility of assuming that the VOC emission rates in real conditions are the same as those in the test chambers.     

Estimated long-term outdoor air pollution concentrations in a cohort study

Several recent studies associated long-term exposure to air pollution with increased mortality. An ongoing cohort study, the Netherlands Cohort Study on Diet and Cancer (NLCS), was used to study the association between long-term exposure to traffic-related air pollution and mortality. Following on a previous exposure assessment study in the NLCS, we improved the exposure assessment methods.Long-term exposure to nitrogen dioxide (NO₂), nitrogen oxide (NO), black smoke (BS), and sulphur dioxide (SO₂) was estimated. Exposure at each home address (N=21 868) was considered as a function of a regional, an urban and a local component. The regional component was estimated using inverse distance weighed interpolation of measurement data from regional background sites in a national monitoring network. Regression models with urban concentrations as dependent variables, and number of inhabitants in different buffers and land use variables, derived with a Geographic Information System (GIS), as predictor variables were used to estimate the urban component. The local component was assessed using a GIS and a digital road network with linked traffic intensities. Traffic intensity on the nearest road and on the nearest major road, and the sum of traffic intensity in a buffer of 100 m around each home address were assessed. Further, a quantitative estimate of the local component was estimated.The regression models to estimate the urban component explained 67%, 46%, 49% and 35% of the variances of NO₂, NO, BS, and SO₂ concentrations, respectively. Overall regression models which incorporated the regional, urban and local component explained 84%, 44%, 59% and 56% of the variability in concentrations for NO₂, NO, BS and SO₂, respectively.We were able to develop an exposure assessment model using GIS methods and traffic intensities that explained a large part of the variations in outdoor air pollution concentrations.     

Land application of tylosin and chlortetracycline swine manure: Impacts to soil nutrients and soil microbial community structure

The land application of aged chortetracycle (CTC) and tylosin-containing swine manure was investigated to determine associated impacts to soil microbial respiration, nutrient (phosphorus, ammonium, nitrate) cycling, and soil microbial community structure under laboratory conditions. Two silty clay loam soils common to southeastern South Dakota were used. Aerobic soil respiration results using batch reactors containing a soil-manure mixture showed that interactions between soil, native soil microbial populations, and antimicrobials influenced CO₂ generation. The aged tylosin treatment resulted in the greatest degree of CO₂ inhibition, while the aged CTC treatment was similar to the no-antimicrobial treatment. For soil columns in which manure was applied at a one-time agronomic loading rate, there was no significant difference in soil-P behavior between either aged CTC or tylosin and the no-antimicrobial treatment. For soil-nitrogen (ammonium and nitrate), the aged CTC treatment resulted in rapid ammonium accumulation at the deeper 40cm soil column depth, while nitrate production was minimal. The aged CTC treatment microbial community structure was different than the no-antimicrobial treatment, where amines/amide and carbohydrate chemical guilds utilization profile were low. The aged tylosin treatment also resulted in ammonium accumulation at 40 cm column depth, however nitrate accumulation also occurred concurrently at 10 cm. The microbial community structure for the aged tylosin was also significantly different than the no-antimicrobial treatment, with a higher degree of amines/amides and carbohydrate chemical guild utilization compared to the no-antimicrobial treatment. Study results suggest that land application of CTC and tylosin-containing manure appears to fundamentally change microbial-mediated nitrogen behavior within soil A horizons.     

Utilization of sepiolite materials as a bottom liner material in solid waste landfills

Landfill bottom liners are generally constructed with natural clay soils due to their high strength and low hydraulic conductivity characteristics. However, in recent years it is increasingly difficult to find locally available clay soils that satisfy the required engineering properties. Fine grained soils such as sepiolite and zeolite may be used as alternative materials in the constructions of landfill bottom liners. A study was conducted to investigate the feasibility of using natural clay rich in kaolinite, sepiolite, zeolite, and their mixtures as a bottom liner material. Unconfined compression tests, swell tests, hydraulic conductivity tests, batch and column adsorption tests were performed on each type of soil and sepiolite–zeolite mixtures. The results of the current study indicate that sepiolite is the dominant material that affects both the geomechanical and geoenvironmental properties of these alternative liners. An increase in sepiolite content in the sepiolite–zeolite mixtures increased the strength, swelling potential and metal adsorption capacities of the soil mixtures. Moreover, hydraulic conductivity of the mixtures decreased significantly with the addition of sepiolite. The utilization of sepiolite–zeolite materials as a bottom liner material allowed for thinner liners with some reduction in construction costs compared to use of a kaolinite-rich clay.     

Life cycle assessment of low impact development technologies combined with conventional centralized water systems for the City of Atlanta,Georgia

Low-impact development (LID) technologies, such as bioretention areas, rooftop rainwater harvesting, and xeriscaping can control stormwater runoff, supply non-potable water, and landscape open space. This study examines a hybrid system (HS) that combines LID technologies with a centralized water system to lessen the burden on a conventional system (CS). CS is defined as the stormwater collection and water supply infrastructure, and the conventional landscaping choices in the City of Atlanta. The study scope is limited to five single-family residential zones (SFZs), classified R-1 through R-5, and four multi-family residential zones (MFZs), classified RG-2 through RG-5. Population density increases from 0.4 (R-1) to 62.2 (RG-5) persons per 1,000 m2. We performed a life cycle assessment (LCA) comparison of CS and HS using TRACI 2.1 to simulate impacts on the ecosystem, human health, and natural resources.We quantified the impact of freshwater consumption using the freshwater ecosystem impact (FEI) indicator. Test results indicate that HS has a higher LCA single score than CS in zones with a low population density; however, the difference becomes negligible as population density increases. Incorporating LID in SFZs and MFZs can reduce potable water use by an average of 50% and 25%, respectively; however, water savings are negligible in zones with high population density (i.e., RG-5) due to the diminished surface area per capita available for LID technologies. The results demonstrate that LID technologies effectively reduce outdoor water demand and therefore would be a good choice to decrease the water consumption impact in the City of Atlanta.

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C-Lock (Patent Pending): A System for Estimating and Certifying Carbon Emission Reduction Credits for the Sequestration of Soil Carbon on Agricultural Land

The C-Lock system was developed to address the need for an improved method of quantifying and certifying project-level carbon emission reduction credits (CERC). It was designed to enable individual landowners to efficiently quantify, certify, pool, market and trade CERCs generated by agricultural management practices. We provide a general overview of the C-Lock system as it has been implemented for the USA State of South Dakota. C-Lock is comprised of four linked components: a web interface, a client database, a Geographic Information System (GIS) database of soil, climate and generalized land use history parameters, and the CENTURY soil carbon model. The user-friendly interface elicits generalized land-use and crop history information from the client from 1900 through 1989, then explicit annual information from 1990 onward. A climate-zone level landuse and crop management database is used to fill in gaps in the client-provided data. These data are used to drive the CENTURY model, which estimates annual changes in soil carbon stocks. Monte Carlo simulation is used to estimate uncertainty bounds, and these are applied to the CENTURY outputs in order to provide probabilistic estimates of accrued CERCs in a manner that is transparent and verifiable. In a demonstration application, CERCs are estimated for three different land-use scenarios on a representative field in eastern South Dakota: reduced tillage or conservation (no-till) management of a corn (maize)/wheat/soybean rotation, and enrollment in the Conservation Reserve Program, which entails establishing permanent grass cover. The credits are based on a business-asusual scenario of conventional tillage.     

Tethered balloon measurements of biogenic VOCs in the atmospheric boundary layer

Biogenic volatile organic compounds (BVOCs) were measured on tethered balloon platforms in 11 deployments between 1985 and 1996. A series of balloon sampling packages have been used to describe boundary layer dynamics, BVOC distribution, chemical transformations of BVOCs, and to estimate BVOC emission rates from terrestrial vegetation. Measurements indicated a slow decrease of concentration for BVOCs with altitude in the mixed layer when sampling times were greater than average convective turnover time; surface layer concentrations were more variable because of proximity to various emission sources in the smaller surface layer footprint. Mixed layer concentrations of isoprene remained fairly constant in the middle of the day, in contrast to canopy-level isoprene concentrations, which continued to increase until early evening. Daytime emissions, which increase with temperature and light, appear to be balanced by changes in entrainment and oxidation. Daytime measurements of methacrolein and methyl vinyl ketone, reaction products of the atmospheric oxidation of isoprene, showed fairly constant ratio to each other with altitude throughout the mixed layer. BVOC emission flux estimates using balloon measurements and from the extrapolation of leaf level emissions to the landscape scale were in good agreement.     

热带人工橡胶林异戊二烯排放通量的模式研究

2 0 0 2年 7月中旬 (湿季 ) ,我们利用快速异戊二烯系统对云南热带森林异戊二烯的排放通量进行了连续测量 ,同时对其影响因子光合有效辐射、气温、湿度、风等参数进行了观测 .研究表明 ,该地区人工橡胶林异戊二烯的排放有明显的日变化 ,云和降水可以明显减小异戊二烯的排放 .利用光合有效辐射守恒的观点处理与植物异戊二烯排放有关的过程 ,建立了一个计算异戊二烯排放的经验模式 ,计算值与观测值比较接近 .因此 ,以一定的物理原理和对实际大气状况观测资料的分析为基础 ,建立异戊二烯排放模式的方法是可行的 .     

The Atmosphere can be a Source of Certain Water Soluble Volatile Organic Compounds in Urban Streams

Surface water and air volatile organic compound (VOC) data from 10 U.S. Geological Survey monitoring sites were used to evaluate the potential for direct transport of VOCs from the atmosphere to urban streams. Analytical results of 87 VOC compounds were screened by evaluating the occurrence and detection levels in both water and air, and equilibrium concentrations in water (C_w^s) based on the measured air concentrations. Four compounds (acetone, methyl tertiary butyl ether, toluene, and m‐ & p‐xylene) were detected in more than 20% of water samples, in more than 10% of air samples, and more than 10% of detections in air were greater than long‐term method detection levels (LTMDL) in water. Benzene was detected in more than 20% of water samples and in more than 10% of air samples. Two percent of benzene detections in air were greater than one‐half the LTMDL in water. Six compounds (chloroform, p‐isopropyltoluene, methylene chloride, perchloroethene, 1,1,1‐trichloroethane, and trichloroethene) were detected in more than 20% of water samples and in more than 10% of air samples. Five VOCs, toluene, m‐ & p‐xylene, methyl tert‐butyl ether (MTBE), acetone, and benzene were identified as having sufficiently high concentrations in the atmosphere to be a source to urban streams. MTBE, acetone, and benzene exhibited behavior that was consistent with equilibrium concentrations in the atmosphere.